VINYLDIMETHYLCHLOROSILANE

Product Code: SIV9070.0
CAS No: 1719-58-0
SDS Sheets: EU | US
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1719-58-0
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250 g
$373.00
750 g
$751.00
16 kg
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150 kg
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Prices listed are EXW price (Morrisville, PA US) in USD. Prices vary depending on currency and Incoterms.

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    217-007-1
  • HMIS

    3-4-1-X
  • Molecular Formula

    C4H9ClSi
  • Molecular Weight (g/mol)

    120.65
  • Purity (%)

    97%
  • TSCA

    Yes
  • Boiling Point (˚C/mmHg)

    82-83
  • Density (g/mL)

    0.884
  • Flash Point (˚C)

    -5 °C
  • Refractive Index @ 20˚C

    1.4137

Additional Properties

  • Hydrolytic Sensitivity

    8: reacts rapidly with moisture, water, protic solvents

    • Application

    Review of synthetic utility.1
    Used in synthesis of highly substituted unsaturated alcohols.2
    Reductively cross-couples with allyl alcohols to form butenols after oxidation.3
    Used to silylate unsaturated alcohols, which can be RCM-cyclized to a vinylsilyl ether, which in turn can be subjected to a silicon-based cross-coupling.4

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 157-161.
    2. Denmark, S. E.; Lang, S. M. Org. Lett. 2001, 3, 1749.
    3. Belardi J. K.; Micalizio, G. C. J. Am. Chem. Soc. 2008, 130, 16870.
    4. Denmark, S. E.; Yang, S.-M. Org. Lett. 2003, 3, 1749.

    Safety

  • Packaging Under

    Nitrogen