METHYLTRICHLOROSILANE, 98%

Product Code: SIM6520.0
CAS No: 75-79-6
SDS Sheets: EU | US
COMMERCIAL
75-79-6
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Quantity
Price
 
cyl
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dr
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4 kg
$244.00
20 kg
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Prices listed are EXW price (Morrisville, PA US) in USD. Prices vary depending on currency and Incoterms.

Product data and descriptions listed are typical values, not intended to be used as specification.

  • Einecs Number

    200-902-6
  • HMIS

    3-4-2-X
  • Molecular Formula

    CH3Cl3Si
  • Molecular Weight (g/mol)

    149.48
  • Purity (%)

    98%
  • TSCA

    Yes
  • Delta H Vaporization (kJ/mol)

    7.4 kcal/mole
  • Autoignition Temp (˚C)

    395
  • Boiling Point (˚C/mmHg)

    66.4
  • Density (g/mL)

    1.275
  • Flash Point (˚C)

    -15 °C
  • Melting Point (˚C)

    -78°
  • Refractive Index @ 20˚C

    1.4110
  • Viscosity at 25 ˚C (cSt)

    0.46

Additional Properties

  • Hydrolytic Sensitivity

    8: reacts rapidly with moisture, water, protic solvents
  • Surface Tension (mN/m)

    20.3
  • Application

    Review of synthetic utility.1
    In a synergistic fashion with boron trifluoride etherate catalyzes the crossed imino aldehyde pinacol coupling.2

    Reference

    1. Handbook of Reagents for Organic Synthesis, Reagents for Silicon-Mediated Organic Synthesis, Fuchs, P. L. Ed., John Wiley and Sons, Ltd., 2011, p. 389-393.
    2. Shimizu, M. et al. Synlett. 2002, 1538.

    Safety

  • Hazard Info

    ihl rat, LDLo: 450 ppm/4H
  • Packaging Under

    Nitrogen
  • Alkyl Silane - Conventional Surface Bonding

    Aliphatic, fluorinated aliphatic or substituted aromatic hydrocarbon substituents are the hydrophobic entities which enable silanes to induce surface hydrophobicity. The organic substitution of the silane must be non-polar. The hydrophobic effect of the organic substitution can be related to the free energy of transfer of hydrocarbon molecules from an aqueous phase to a homogeneous hydrocarbon phase. A successful hydrophobic coating must eliminate or mitigate hydrogen bonding and shield polar surfaces from interaction with water by creating a non-polar interphase. Although silane and silicone derived coatings are in general the most hydrophobic, they maintain a high degree of permeability to water vapor. This allows coatings to breathe and reduce deterioration at the coating interface associated with entrapped water. Since ions are not transported through non-polar silane and silicone coatings, they offer protection to composite structures ranging from pigmented coatings to rebar reinforced concrete. A selection guide for hydrophobic silanes can be found on pages 22-31 of the Hydrophobicity, Hydrophilicity and Silane Surface Modification brochure.

    Methyltrichlorosilane; Trichloromethylsilane; Trichlorosilylmethane

  • Viscosity: 0.46 cSt
  • ΔHvap: 31.0 kJ/mol
  • Surface tension: 20.3 mN/m
  • Ionization potential: 11.36 eV
  • Specific heat: 0.92 J/g/°
  • Vapor pressure, 13.5 °C: 100 mm
  • Critical temperature: 243 °C
  • Critical pressure: 39 atm
  • Coefficient of thermal expansion: 1.3 x 10-3
  • Fundamental builing-block for silicone resins
  • Forms silicon carbide by pyrolysis
  • In a synergistic fashion with boron trifluoride etherate catalyzes the crossed imino aldehyde pinacol coupling
  • Higher purity grade available, SIM6520.1